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http://nopr.niscpr.res.in/handle/123456789/46202| Title: | Surface-mediated autoxidation of aqueous SO2 in ceramic powder suspensions |
| Authors: | Bhargava, Rachna Rani, Ashu Gupta, K S |
| Issue Date: | Sep-1992 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | In acetate buffered ceramic suspensions, if the ceramic concentration is not too high, the kinetics
of autoxidation conforms to the rate law Robs = Run + k5[H+]-1[Ceramic][S(IV)]2 where Run is the rate of uncatalyzed reaction and k5 is the rate constant for the surface catalyzed path. The rate of autoxidation is unaffected by oxygen partial pressure. Interestingly, the rate versus [ceramic] profile passes through a maximum indicating that the autoxidation mechanism involves the adsorption of both sulphur(IV) and dioxygen on particle surface. |
| Page(s): | 683-687 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.31A(09) [September 1992] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 31A(9) 683-687.pdf | 541.73 kB | Adobe PDF | View/Open |
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