Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/46210| Title: | Contrasting isomer stabilities of silaboranes and carboranes : Si2B3H5 and C2B3H5 isomers |
| Authors: | Jemmis, Eluvathingal D Subramanian, G |
| Issue Date: | Sep-1992 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The relative stabilities of the isomers of closo- Si2B3H5 have been calculated at the MNDO, HF/6- 31G* and MP2/6-3IG* levels. Contrary to the results for the corresponding carborane C2B3H5 reported earlier, Si2B3H5 is predicted to be the most stable. The concept of the compatibility of orbitals in overlap is used to rationalize our observation of this reversal of trends in isomer stabilities. |
| Page(s): | 645-646 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.31A(09) [September 1992] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 31A(9) 645-646.pdf | 208.62 kB | Adobe PDF | View/Open |
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.