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dc.contributor.authorLakshmanan, Vasanthi-
dc.contributor.authorNagaraja, K.S.-
dc.contributor.authorUdupa, M R-
dc.date.accessioned2019-03-20T05:15:09Z-
dc.date.available2019-03-20T05:15:09Z-
dc.date.issued1992-10-
dc.identifier.issn0975-0975(Online); 0376-4710(Print)-
dc.identifier.urihttp://nopr.niscair.res.in/handle/123456789/46212-
dc.description806-807en_US
dc.description.abstractThe complex Mo2O4(dto)2 (dto = dithiooxamide) has a magnetic moment of 0.51B.M. The electronic spectral data (450 nm) indicate the presence of Mo2O42+ core. The negative shifts (50 cm-1) and spitting  in v(CN) and v(CS) bands indicate the uninegative bidentate nature of dithiooxamide. The bands at 970, 740 and 480 cm-1 indicate the presence of terminal (Mo=O1) and bridging (MoOb) Mo groups. The complex exhibits and irreversible cathodic wave (-1.30 vs SCE) characteristic of a Mo2O42+ core. A di-μ-oxo bridged structure with dithiooxamide completing five coordination around each Mo is proposed.en_US
dc.language.isoen_USen_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.rights CC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.31A(10) [October 1992]en_US
dc.titleSynthesized and characterization of oxomolybdenum(V) complex with dithiooxamideen_US
dc.typeArticleen_US
Appears in Collections:IJC-A Vol.31A(10) [October 1992]

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