Please use this identifier to cite or link to this item: http://nopr.niscpr.res.in/handle/123456789/46218
Title: Olefin epoxidation using iron (III) schiff base complexes as catalyst
Authors: Agarwal, D D
Jain, R
Rastogi, R
Agarwal, Vinita
Issue Date: Oct-1992
Publisher: NISCAIR-CSIR, India
Abstract: The epoxidation of cyclohexene gives cyclohexene oxide, cyclohexenol and cyclohexenone as the products. The addition of pyridine as axial ligand promotes the yield. The addition of SLS increases the epoxide yield while addition of Triton-X-100 and CTABr retards the yield. The relative rates of cycloolefin follow the order norbornene > cycloheptene > cyclohexene suggesting that olefin is not coordinated to metal center in the rate determining step.
Page(s): 785-787
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.31A(10) [October 1992]

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