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http://nopr.niscpr.res.in/handle/123456789/46261| Title: | Kinetics and mechanism of oxidation of substituted ethanols by bromamine-T in acid medium |
| Authors: | Puttaswamy Mahadevappa, D S |
| Issue Date: | Jan-1990 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The kinetics of oxidation of seven primary alcohols, RCH2CH2OH (where R = -H, -OC2H5, -OCH3, -NH2, -Cl, -Br and –NO2) by bromamine-T in the presence of HCl has been studied at 45°. The rates show first order dependence on [BAT] and fractional order each on [alcohol]0, [H+] and [Cl-]. Variations of ionic strength and dielectric constant of the medium and addition of reaction product (toluenesulphonamide) have no effect on the rate. Formation constants and decomposition constants of alcohol- BAT complexes have been determined. The rates do not correlate satisfactorily with Taft substituent constants. |
| Page(s): | 42-45 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.29A(01) [January 1990] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 29A(1) 42-45.pdf | 873.47 kB | Adobe PDF | View/Open |
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