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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Dash, Anadi C | - |
| dc.contributor.author | Das, Smrutiprava | - |
| dc.contributor.author | Nanda, Rabindra K | - |
| dc.date.accessioned | 2019-03-20T11:44:33Z | - |
| dc.date.available | 2019-03-20T11:44:33Z | - |
| dc.date.issued | 1990-03 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://nopr.niscair.res.in/handle/123456789/46314 | - |
| dc.description | 227-230 | en_US |
| dc.description.abstract | The (ɑβS) [(tetren)CoO2CCH2NH3]3+ ion undergoes hydrolysis at 25-40ᵒC and pH = (6.9-8.2 via a single kinetic-controlled path. The high rate of spontaneous aquation of the glycinato complex, in contrast to the extreme inertness of its N-protonated form to aquation, is consistent with the operation of an intramolecular conjugate base mechanism (SNICB) involving the generation of a reactive conjugate base via the NH - deprotonation of the amine function of the coordinated tetren ligand by the unbound – NH2 group of the glycine ligand. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.29A(03) [March 1990] | en_US |
| dc.title | Kinetics and mechanism of hydrolysis of (ɑβS)-(glycinato-O) (tetraethylenepentamine)cobalt (III) ion | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.29A(03) [March 1990] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 29A(3) 227-230.pdf | 255.4 kB | Adobe PDF | View/Open |
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