Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/46327| Title: | Kinetics and mechanism of silver (I) catalysed oxidation of chromium (III) by peroxodiphosphate in acetate buffers |
| Authors: | Parashar, Pradeep Sharma, P D Gupta, Y K |
| Issue Date: | Apr-1990 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | In the title reaction the rate is independent of the [reductant] and occurs by the redox cycle Ag(I)/ Ag(II) through four steps: H2P2O + Ag+ (k1); H2P2O + AgO2CCH3 (k'1); HP2O + Ag+ (k'2); HP2O + AgO2CCH3 (k'2). k1, k'l, k2 and k'2 (dm3mol-1s-l) are 0.017, 0.069, 0.19 and 0.36, respectively at 40ᵒ and ionic strength = 1.0 mol dm-3. |
| Page(s): | 383-386 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.29A(04) [April 1990] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 29A(4) 383-386.pdf | 716.67 kB | Adobe PDF | View/Open |
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