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http://nopr.niscpr.res.in/handle/123456789/46335| Title: | Synthesis and reactivity of some boron heterocycles derived from hydroxamic acids |
| Authors: | Das, Mrinal K Chakraborty, Susanta |
| Issue Date: | Apr-1990 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | A series of boron compounds of the general formula [R' (OH)2 has been synthesised by the reaction of trimethoxyboroxine with hydroxamic acids, R'CONROH (R = H, aryl; R' = aryl), in aqueous alcoholic medium. These have been characterized by elemental analyses, UV, IR, NMR (1H and 11B) spectra and molecular weight data. The boron compounds are nonelectrolytes in DMSO and nitromethane. These heterocycles react with oxalic acid, malonic acid, catechol and ethylene glycol to give spiro compounds, which have been characterized. |
| Page(s): | 352-355 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.29A(04) [April 1990] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 29A(4) 352-355.pdf | 835.98 kB | Adobe PDF | View/Open |
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(OH)2 has been synthesised by the reaction of trimethoxyboroxine with hydroxamic acids, R'CONROH (R = H, aryl; R' = aryl), in aqueous alcoholic medium. These have been characterized by elemental analyses, UV, IR, NMR (1H and 11B) spectra and molecular weight data. The boron compounds are nonelectrolytes in DMSO and nitromethane. These heterocycles react with oxalic acid, malonic acid, catechol and ethylene glycol to give spiro compounds, which have been characterized.