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http://nopr.niscpr.res.in/handle/123456789/46378| Title: | Mechanism of ruthenium(III) catalysed oxidation of some alcohols by hexacyano-ferrate( III) in mild alkaline medium |
| Authors: | Singh, M P Tandon, P K Mehrotra, Alka Gupta, Arti Singh, Rekha |
| Issue Date: | Jun-1990 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Ruthenium (III) chloride catalysed oxidation of propanol-1, butanol-1, propanol-2 and butanol-2 by hexacyanoferrate (III) in sodium carbonate medium is zero order in [hexacyanoferrate (III)]. Rate of the reaction is directly proportional to [alcohol] and [OH-] in the low concentration regions. After reaching a maximum value further addition of either of these retards the rate. Increase in pH of the medium retards the rate. On the basis of the results obtained a probable reaction path has been suggested. |
| Page(s): | 590-591 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.29A(06) [June 1990] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 29A(6) 590-591.pdf | 160.79 kB | Adobe PDF | View/Open |
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