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http://nopr.niscpr.res.in/handle/123456789/46388Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Mandal, Sisir K | - |
| dc.contributor.author | Chakravarty, Akhil R | - |
| dc.date.accessioned | 2019-03-22T07:21:09Z | - |
| dc.date.available | 2019-03-22T07:21:09Z | - |
| dc.date.issued | 1990-06 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://nopr.niscair.res.in/handle/123456789/46388 | - |
| dc.description | 552-555 | en_US |
| dc.description.abstract | Cyclopentadienyl-bis(triphenylphosphine) carboxylatoruthenium(II) compounds, Ru(η- C5H5)(PPh3)2(O2CR) have been prepared by reacting Ru(η-C5H5)(PPh3)2Cl and AgO2CR [R=Me, C6H4-p-X (X = H, Me, OMe, NO2 and Cl)] in benzene. The 18-electron compounds are moderately stable and contain a unidentate carboxylato ligand. Cyclic voltammetry of these compounds shows the presence of a one-electron ruthenium(II)/ruthenium(m) couple near 0.6V (vs SCE) in CH2Cl2. The half-wave potentials follow the Hammett linear free energy relationship when plotted against the σ-values of the substituents. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.29A(06) [June 1990] | en_US |
| dc.title | Synthesis, structure and redox properties of Ru(η-C5H5)(PPh3)2 (O2CR) | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.29A(06) [June 1990] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 29A(6) 552-555.pdf | 297.69 kB | Adobe PDF | View/Open |
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