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http://nopr.niscpr.res.in/handle/123456789/46407| Title: | Kinetics of oxidation of cinnamaldehyde by chloramine-T in perchloric acid and in alkaline medium catalysed by Os(VIII) |
| Authors: | Mythily, C K Rangappa, K S Mahadevappa, D S |
| Issue Date: | Jul-1990 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Kinetics of chloramines-T (CAT) oxidation of cinnamaldehyde in acid medium and in alkaline medium (catalysed by OsO4) have been investigated at 313 K. In acid medium, a Michaelis-Menten kinetics is obeyed with a first order dependence of rate on [CAT] and a fractional order in [aldehyde] which becomes zero at higher [aldehyde]. Rate dependence on [H+] varies from inverse fractional to fractional order. In alkaline medium the reaction in first order each in [CAT] and [Os(VIII)] and inverse first order in [OH-]. Solvent isotope effect, effects of added chloride ion, and p-toluenesulphonamide and varying ionic strength and dielectric constant of medium have been investigated. Activation parameters have been computed. |
| Page(s): | 676-679 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.29A(07) [July 1990] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 29A(7) 676-679.pdf | 326.52 kB | Adobe PDF | View/Open |
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