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http://nopr.niscpr.res.in/handle/123456789/46410| Title: | Synthesis and NMR spectral studies of polynuclear complexes of rhodium(I) with bridging benzimidazole derivatives |
| Authors: | Halesha, R Gowda, N M N Reddy, G K N |
| Issue Date: | Jul-1990 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Reaction of [Rh(diolefin)(μ-C!]2 (diolefin = cycloocta-1, 5-diene or norbornadiene) with 2-substituted benzimidazoles (R-bztH; R = H, Me, Et, n-Pr or n-Bu) in the presence of triethylamine yields trinuclear complexes of the type [Rh(diolefin)(μ-R-bzt)3. The latter compounds undergo displacement of diolefin with CO to give tetranuclear complexes of the formula [Rh(CO)2(μ-R-bzt)4. NMR spectral studies have been useful in assigning the structures of the complexes. |
| Page(s): | 661-665 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.29A(07) [July 1990] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 29A(7) 661-665.pdf | 342.2 kB | Adobe PDF | View/Open |
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