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http://nopr.niscpr.res.in/handle/123456789/46421Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Barhate, V D | - |
| dc.contributor.author | Patil, M R | - |
| dc.date.accessioned | 2019-03-22T09:48:19Z | - |
| dc.date.available | 2019-03-22T09:48:19Z | - |
| dc.date.issued | 1990-08 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://nopr.niscair.res.in/handle/123456789/46421 | - |
| dc.description | 827-828 | en_US |
| dc.description.abstract | p-Methylisonitrosoacetophenone (HIMAP) extracts Pd(II)quantitatively (99.87%)into chloroform from aqueous solutions of pH 0-4 and from solutions containing 0.1 to 1 M acetic acid and mineral acids except HCl. The chloroform extract shows λmax values at 340 and 415 nm. Beer's law is obeyed over the Pd(II) concentration range 0.1-10 μg/ml. The molar absorptivity is 15,810 I mol-1 cm-1 and the sensitivity is 6.7 ng cm-2 at 415 nm. The composition of extracted species is found to be 1:2 (Pd:HIMAP) by Job's continuous variation, mole ratio and slope methods. Interference by various ions has been studied. The proposed method has been applied to the determination of Pd(II) in silver alloy and Pd-catalyst wastes. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.29A(08) [August 1990] | en_US |
| dc.title | Extraction and direct spectrophotometric determination of palladium(II) with p- methylisoni trosoacetophenone | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.29A(08) [August 1990] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 29A(8) 827-828.pdf | 155.26 kB | Adobe PDF | View/Open |
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