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http://nopr.niscpr.res.in/handle/123456789/46430| Title: | Convenient synthesis of hexakis(dimethyl sulphoxide)ruthenium(III) and tetra(halogeno) bis( dimethyl sulphoxide)ruthenate(III) |
| Authors: | Sarma, Uma Charan Paul, Bipul Chandra Poddar, Raj K |
| Issue Date: | Aug-1990 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Cationic and anionic complexes of ruthenium(III), viz., [Ru(Me2SO)6]X3 (X=ClO4 or BPh4) and NR4[RuX4(Me2SO)2] (R = Me, X = Cl; R = Et, X = Br) have been synthesized and characterized by IR, UV-visible and EPR spectroscopy, magnetic susceptibility and molar conductance measurements. [Ru(Me2SO)6]3+ has three S-bonded and three O-bonded Me2SO molecules, arranged in a facial octahedral geometry around the metal ion. The anionic complexes possess cis geometry, the coordination of Me2SO being through the S-atom in the chloro complex and through the O-atom in the bromo analogue. |
| Page(s): | 803-805 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.29A(08) [August 1990] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 29A(8) 803-805.pdf | 251.31 kB | Adobe PDF | View/Open |
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