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http://nopr.niscpr.res.in/handle/123456789/46444| Title: | Studies on preparation, characterisation and metal-ion assisted aquation of [Co(pn)(dien)X]X2·H2O (X = Cl, Br) |
| Authors: | Bhat, G R Dubey, K P Segal, B Pierpont, C G |
| Issue Date: | Aug-1990 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Chloro and bromo complexes of the type [Co(pn)(dien)X]X2·H2O (X = Cl, Br) have been synthesized and found to have unsymmetrical fac-configuration from their 13C NMR data. Kinetic parameters for aquation of these complexes have been determined in nitric acid medium at constant ionic strength (μ = 1.0 mol dm-3). It is found that the bromo complex reacts faster than the chloro complex and the efficacies of the metal-ions follow the order: Hg > Ag+. |
| Page(s): | 745-747 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.29A(08) [August 1990] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 29A(8) 745-747.pdf | 236.27 kB | Adobe PDF | View/Open |
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