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http://nopr.niscpr.res.in/handle/123456789/46514| Title: | Molecular addition complexes of organo-titanium(IV), -tin(IV) and -lead(IV) chlorides with dithiocarbazate schiff bases |
| Authors: | Gopinathan, (Mrs) Sarada Degaonkar, (Mrs) M P Gopinathan, C |
| Issue Date: | Oct-1990 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Reactions of organo-titanium(IV), -tin(IV) and -lead(IV) chlorides with dithiocarbazate schiff bases in 1:1 molar ratio yield to brown solid molecular addition complexes of the type R2MCl2 (Schiff base) and Ph3MCI (schiff base). The structures of these adducts have been assigned based on elemental analyses, IR and 1H NMR data. The former type of complexes have been found to have hexa-coordinated structures with bidentate N-S coordination, whereas the latter type possess penta-coordination with nitrogen coordinated schiff base. The PhSnCl3 (schiff base) adducts have been found to belong to the former class. |
| Page(s): | 971-976 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.29A(10) [October 1990] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 29A(10) 971-976.pdf | 4.24 MB | Adobe PDF | View/Open |
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