Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/46613| Title: | Extractive Spectrophotometric Determination of Palladium(II} Using Mixed Ligand Complex Formation with Pyridine/ɑ-Picoline/β-Picoline/γ-Picoline/2, 4, 6-Collidine & Iodide |
| Authors: | Thokdar, T K Sarkar, A Paria, P K Majumdar, S K |
| Issue Date: | Feb-1989 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Palladium(II) forms complexes with pyridine/ɑ-picoline/β- picoline/γ-picoline/2,4,6-collidine in presence of potassium iodide. These are extractable into chloroform and absorb at 354- 360 nm. The molar absorptivities of the complexes are in the range 1.6-1.9 x 104 l mol-1 cm-1. The formation of these complexes has been utilized to propose an extractive spectrophotometric method of determination of palladium. The notable metal interference is due to mercury. Use of other common organic solvents provides no special advantages. |
| Page(s): | 181-182 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.28A(02) [February 1989] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 28A(2) 181-182.pdf | 1.26 MB | Adobe PDF | View/Open |
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.