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http://nopr.niscpr.res.in/handle/123456789/46633Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Radhakrishnamurti, P S | - |
| dc.contributor.author | Panigrahi, J C | - |
| dc.date.accessioned | 2019-03-26T04:35:15Z | - |
| dc.date.available | 2019-03-26T04:35:15Z | - |
| dc.date.issued | 1989-02 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://nopr.niscair.res.in/handle/123456789/46633 | - |
| dc.description | 124-128 | en_US |
| dc.description.abstract | Kinetics of chlorination of aniline by trichloromelamine (TCM) in aqueous acetic acid medium, over the temperature range 30°-45°C and solvent composition from 1% to 100% acetic acid have been reported. The orders of reaction in [substrate], [oxidant] and [acid], and the effect of neutral salts like KCI and melamine have been evaluated in 50%, 90% and 100% acetic acid. The results show a novel dependence of chlorinating agent on the nature of solvent system. Kendall's treatment has been applied to compute the acid-independent rate constants with respect to substrate. Plausible mechanisms are suggested. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.28A(02) [February 1989] | en_US |
| dc.title | Kinetics & Mechanism of Chlorination of Aniline by Trichloromelamine in Aqueous Acetic Acid-Perchloric Acid Medium: A Novel Dependence of Chlorinating Agent on Nature of Solvent System (Part 1) | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.28A(02) [February 1989] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 28A(2) 124-128.pdf | 2.77 MB | Adobe PDF | View/Open |
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