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http://nopr.niscpr.res.in/handle/123456789/46634| Title: | Kinetics of Chlorination of Aniline by Dichloramine-T in Aqueous Acetic Acid Medium |
| Authors: | Gowda, B Thimme Sherigara, B S |
| Issue Date: | Feb-1989 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Chlorination of aniline by dichloramine-T in 1:1 aqueous acetic acid medium, in the presence and absence of acetate ions is first order in [oxidant], nearly first order in [aniline], inverse fractional order in [H+] and fractional order in added [acetate ion] at constant ionic strength. Effects of added reaction products and variations in ionic strength and solvent composition of the reaction medium have also been investigated. Mechanisms consistent with the observed results are discussed and the related rate laws deduced. |
| Page(s): | 120-123 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.28A(02) [February 1989] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 28A(2) 120-123.pdf | 2.27 MB | Adobe PDF | View/Open |
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