Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/46645| Title: | Kinetics & mechanism of oxidation of dimethyl, methyl phenyl & diaryl sulphoxides by N-bromocaprolactam |
| Authors: | Srinivasan, C Jegatheesan, P Pandarakutty |
| Issue Date: | Mar-1989 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The oxidation of dimethyl (DMSO) and methyl phenyl (MPSON) sulphoxides by N-bromocaprolactam (NBC) follows zero order kinetics in [sulphoxide], but that of diphenyl sulphoxide (DPSO) is first order in [DPSO] HClO4 accelerates the rate of all the oxidation reactions. However, added caprolactam retards the oxidation of only DPSO. |
| Page(s): | 250-252 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.28A(03) [March 1989] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 28A(3) 250-252.pdf | 1.7 MB | Adobe PDF | View/Open |
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.