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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Gopinathan, (Mrs) Sarada | - |
| dc.contributor.author | Unni, I R | - |
| dc.contributor.author | Gopinathan, C | - |
| dc.date.accessioned | 2019-03-26T05:22:58Z | - |
| dc.date.available | 2019-03-26T05:22:58Z | - |
| dc.date.issued | 1989-04 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://nopr.niscair.res.in/handle/123456789/46669 | - |
| dc.description | 331-332 | en_US |
| dc.description.abstract | Ruthenium(II) and rhodiumil) precursors namely RuHCl(CO)(PPh3)3], [Ru(CO)2Cl2]n, [RuCl2(PPh3)3] and [RhH(PPh3)4 react with 2-hydroxypyridine (PyOH) and 6-methyl-2-hydroxypyridine (MePyOH) to afford a range of novel mononuclear complexes, namely [RuCl(CO)(PyO)(PPh3)2], [RuH(CO)(PyO)(PPh3)2], [RuCl(CO)(MePyO)(PPh3)2], [RuH(CO)(MePyO)(PPh3)2], [Ru(MePyO)2(PPh3)2], [Ru(CO)2(PyO)2], [Rh(PyO)(PPh3)2] and [Rh(MePyO)(PPh3)2]. In these complexes the oxypyridines are bound in bidentate (N,O-chelate) mode. The complexes have been characterized by analytical, IR and 1H NMR data. Evidences indicate that [RuH/Cl(CO)(PyO/MePyO)(PPh3)2] complexes exist in two geometrical isomeric forms. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.28A(04) [April 1989] | en_US |
| dc.title | Ruthenium{II} & rhodiurrul) complexes of 2-hydroxypyridinest | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.28A(04) [April 1989] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 28A(4) 331-332.pdf | 1.35 MB | Adobe PDF | View/Open |
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