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http://nopr.niscpr.res.in/handle/123456789/46683| Title: | Redox chemistry of hyponitrite: Part III-oxidation by hexacyanoferrate(III) in aqueous alkaline solution |
| Authors: | Goyal, M R Bhatnagar, Pankaj Mittal, R K Gupta, Y K |
| Issue Date: | Apr-1989 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Oxidation of hyponitrite by hexacyanoferrate(III) in alkaline solution occurs by two paths resulting in a stoichiometry of 1.21:1(oxidant:substrate). The final products are N2O,N2 and NO , and the intermediates are NO and peroxonitrite. Rate has first order dependence in [Fe(CN) ] and [(N2O ] and no dependence on [OH-]. The second order rate constant is found to be (0.87 ± 0.025) dm3 mol-1 at 35° and 1= 0.515 mol dm-3. Rate significantly increases in the presence of alkali metal cations. |
| Page(s): | 280-283 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.28A(04) [April 1989] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 28A(4) 280-283.pdf | 2.03 MB | Adobe PDF | View/Open |
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