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http://nopr.niscpr.res.in/handle/123456789/46694| Title: | Hydrolysis of 4-chloro-3,5-dimethylphenyl phosphate monoester in acid solutions |
| Authors: | Mhala, M M Kushwaha, R S |
| Issue Date: | May-1989 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Hydrolysis of 4-chloro-3,5-dimethylphenyl phosphate monoester has been carried out in HCI solution at 98 ± 5ᵒC and the inorganic phosphate obtained during hydrolysis has been estimated calorimetrically. Pseudo first order rate coefficients have been calculated. Neutral species have been found to be reactive and contribute to overall hydrolysis in the acid region. The calculated rate coefficients are in good agreement with the experimentally observed ones. The effects of temperature, solvent and [substrate] on the rate have been studied. The results suggest that the hydrolysis of monoester occurs by the cleavage of P-O bond. |
| Page(s): | 420-421 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.28A(05) [May 1989] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 28A(5) 420-421.pdf | 1.46 MB | Adobe PDF | View/Open |
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