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http://nopr.niscpr.res.in/handle/123456789/46695Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Radhakrishnamurti, P S | - |
| dc.contributor.author | Panigrahi, J C | - |
| dc.date.accessioned | 2019-03-26T06:16:10Z | - |
| dc.date.available | 2019-03-26T06:16:10Z | - |
| dc.date.issued | 1989-05 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://nopr.niscair.res.in/handle/123456789/46695 | - |
| dc.description | 417-419 | en_US |
| dc.description.abstract | Kinetics of chlorination of some substituted anilines like p-toluidine, p-chloroaniline, p-nitroaniline, N-methylaniline and N,N-dimethylaniline by trichloromelamine (TCM) in 50% and 90% aq. HOAc and 100% HOAc have been studied. In 50% HOAc second order dependence in [TCM] is observed for all the activated amines studied except p-nitroaniline where a first order dependence is noticed. In 90% aq. HOAc and 100% HOAc, first order dependence in [TCM] is observed for all the substrates. Kendall's treatment is applied to compute acid- independent rate constants and structure-reactivity is discussed. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights | CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.28A(05) [May 1989] | en_US |
| dc.title | Novel dependence of chlorinating agent on nature of substrate during chlorination of some aromatic amines by trichloromelamine in aqueous HOAc-HClO4 | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.28A(05) [May 1989] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 28A(5) 417-419.pdf | 1.72 MB | Adobe PDF | View/Open |
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