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http://nopr.niscpr.res.in/handle/123456789/46717Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Mishra, Pranati | - |
| dc.contributor.author | Khandual, N C | - |
| dc.date.accessioned | 2019-03-26T07:04:26Z | - |
| dc.date.available | 2019-03-26T07:04:26Z | - |
| dc.date.issued | 1989-06 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://nopr.niscair.res.in/handle/123456789/46717 | - |
| dc.description | 526-527 | en_US |
| dc.description.abstract | The kinetics of Ag(I) catalysed oxidation of chalcone and seven substituted chalcones have been studied in acetic atid-water mixture (30% v/v) at constant ionic strength. The reaction is first order each in [peroxydisulphate] and [silver(I)] and the rate is independent of [chalcone]. Added allyl acetate inhibits the reaction. The thermodynamic parameters have been evaluated. The log k values have been fitted with σ+ values and the value of ρ+ has been calculated. The rate law has been explained on the basis of free radical mechanism involving silver(I). | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.28A(06) [June 1989] | en_US |
| dc.title | Kinetics of oxidation of chalcones by peroxydisulphate catalysed by silvert(l) ions | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.28A(06) [June 1989] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 28A(6) 526-527.pdf | 1.19 MB | Adobe PDF | View/Open |
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