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http://nopr.niscpr.res.in/handle/123456789/46718Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Mishra, Pranati | - |
| dc.contributor.author | Khandual, N C | - |
| dc.date.accessioned | 2019-03-26T07:05:30Z | - |
| dc.date.available | 2019-03-26T07:05:30Z | - |
| dc.date.issued | 1989-06 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://nopr.niscair.res.in/handle/123456789/46718 | - |
| dc.description | 523-525 | en_US |
| dc.description.abstract | Ag(I) catalysed peroxydisulphate oxidation of benzylphenylglycollic and substituted benzylphenylglycollic acids in acetic acid-water mixture (30% v/v) at constant ionic strength is first order each in [peroxydisulphate] and [Ag(I)] and independent of [reductant]. Addition of allyl acetate inhibits the reaction. The thermodynamic parameters have been evaluated. The log k1 values have been fitted With σ+ values and the value of ρ+ calculated. The rate laws have been proposed on the basis of free radical mechanism involving silver(I). | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.28A(06) [June 1989] | en_US |
| dc.title | Kinetics of silver(I) catalysed peroxydisulphate oxidation of benzylphenyl-glycollic Acids | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.28A(06) [June 1989] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 28A(6) 523-525.pdf | 1.93 MB | Adobe PDF | View/Open |
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