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http://nopr.niscpr.res.in/handle/123456789/46768| Title: | Structure-reactivity correlations in the reactions of phenacyl bromide and ethyl bromoacetat with ortho-substituted cinnamate ions |
| Authors: | Shunmugasundaram, A Chandrasekaran, C R |
| Issue Date: | Aug-1989 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The second order rate constants in the title reactions in 90% acetone-10% water (v/v) mixture at three different temperatures indicate that electron-releasing substituents accelerate the rate while electron-withdrawing substituents retard the rate. A good Hammett correlation with σp constants is obtained for ortho-substituted cinnamate ions. The rate data have also been analysed using the method of Charton. |
| Page(s): | 707-708 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.28A(08) [August 1989] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 28A(8) 707-708.pdf | 1.39 MB | Adobe PDF | View/Open |
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