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http://nopr.niscpr.res.in/handle/123456789/46778Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Char, P Narasimha | - |
| dc.contributor.author | Sondu, S | - |
| dc.contributor.author | Sethuram, B | - |
| dc.contributor.author | Rao, T Navaneeth | - |
| dc.date.accessioned | 2019-03-26T09:58:43Z | - |
| dc.date.available | 2019-03-26T09:58:43Z | - |
| dc.date.issued | 1989-08 | - |
| dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
| dc.identifier.uri | http://nopr.niscair.res.in/handle/123456789/46778 | - |
| dc.description | 670-672 | en_US |
| dc.description.abstract | The kinetics of oxidation of methyl, ethyl and n-butyl acetates by bromate in aq. H2SO4 is first order in both [Br(V)] and [ester] and second order in [H+]. The rate increases with decrease in the dielectric constant of the medium. From the effect of [H+] and [HOAc] on rate, BrO2 is established as the reactive species. Electron releasing groups in ester moiety increase the rate and vice versa with a ρ*-value = - 2.1. A mechanism involving direct oxidation of ester before hydrolysis by bromate has been proposed and verified. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | NISCAIR-CSIR, India | en_US |
| dc.rights |  CC Attribution-Noncommercial-No Derivative Works 2.5 India | en_US |
| dc.source | IJC-A Vol.28A(08) [August 1989] | en_US |
| dc.title | Kinetics and mechanism of oxidation of some aliphatic esters by bromate in acid medium | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.28A(08) [August 1989] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 28A(8) 670-672.pdf | 1.75 MB | Adobe PDF | View/Open |
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