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http://nopr.niscpr.res.in/handle/123456789/46809| Title: | Redox behaviour of o-chlorophenol in aqueous solutions |
| Authors: | Sharma, L R Singh, Gurcharan Sharma, Arun |
| Issue Date: | Sep-1989 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Cyclcic voltammetry (anodic) of o-chlorophenol has been carried out in six background solutions having different acidities. The first forward scan exhibits a single oxidation peak in each case. During the subsequent cyclic operation, three additional redox couples appear in sulphuric acid solutions of concentrations 1.0 M and 0.1 M, two redox couples appear in buffer of pH 4.5 and one redox couple appears in buffers of pH 6.0 and 8.5. A plausible explanation for this typical redox behaviour which is considerably different from that of phenol and o-cresol has been offered on the basis of free radical couplings followed by acid-favoured intramolecular rearrangements in the reaction intermediates. |
| Page(s): | 757-759 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.28A(09) [September 1989] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 28A(9) 757-759.pdf | 1.85 MB | Adobe PDF | View/Open |
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