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http://nopr.niscpr.res.in/handle/123456789/46823| Title: | Substitution reaction of aquo ligands from cis-diaquo-bis(biguanide)- chromium(III) ion with picolinic acid in aqueous medium: Kinetics and mechanism |
| Authors: | Gangopadhyay, A K De, G S |
| Issue Date: | Oct-1989 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Kinetics of substitution of aquo ligands from cis-diaquo- bis(biguanide)chromium(III) ion by picolinic acid in aqueous medium has been studied spectrophotometrically. Activation parameters have been calculated and compared with other substitution reactions of the same complex. Considering the results a mechanism involving the prior formation of ion pair followed by associative interchange (Ia) has been suggested. |
| Page(s): | 899-901 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.28A(10) [October 1989] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 28A(10) 899-901.pdf | 1.67 MB | Adobe PDF | View/Open |
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