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http://nopr.niscpr.res.in/handle/123456789/46859| Title: | Cationic complexes of palladium(II) containing phosphorus, arsenic, antimony and nitrogen donor ligands |
| Authors: | Nagasundara, K R Gowda, N M Nanje Reddy, G K N |
| Issue Date: | Nov-1989 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Palladium perchlorate reacts with several monodentate tertiary phosphines or arsines in acetonitrile to produce three-coordinate complexes of the type [PdL3[ClO4]2 (L= Ph3P, Ph2EtP, Ph3As, Ph2MeAs, Nap2MeAs, Cy3As, Ph3Sb), while the reaction in tetrahydrofuran leads to four-coordinate complexes of the formula [PdL4][ClO4]2 (L= Ph3P, Ph3As, Ph3Sb). With chelating bidentate ligands, palladium perchlorate yields [Pd(L-L)2][ClO4]2 (L-L= diphos, ɑ-pybzl) complexes. |
| Page(s): | 1001-1003 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.28A(11) [November 1989] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 28A(11) 1001-1003.pdf | 1.38 MB | Adobe PDF | View/Open |
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