Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/46891| Title: | Mechanism of oxidation of s-butylamine by alkaline chloramine-T |
| Authors: | Gupta, Jyoti Agrawal, M C |
| Issue Date: | Dec-1989 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Oxidation of s-butylamine (SBA) by chloramine-T (CAT) is first order each in [CAT], [SBA] and the rate is proportional to 1/[OH-] at lower [amine] and higher [alkali]. Salt and solvent effects are negligible. Added toluene sulphonamide slightly accelerates the rate of reaction. A suitable mechanism involving the rate-determining reaction between N-chlorotoluene-p-sulphonamide and SBA has been proposed. |
| Page(s): | 1100-1102 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.28A(12) [December 1989] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 28A(12) 1100-1102.pdf | 1.62 MB | Adobe PDF | View/Open |
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