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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Srivastava, A K | - |
| dc.contributor.author | Chaurasia, A K | - |
| dc.contributor.author | Sharma, Saroj | - |
| dc.contributor.author | Mishra, Garima | - |
| dc.date.accessioned | 2009-06-26T05:34:19Z | - |
| dc.date.available | 2009-06-26T05:34:19Z | - |
| dc.date.issued | 2006-06 | - |
| dc.identifier.issn | 0975-1084 (Online); 0022-4456 (Print) | - |
| dc.identifier.uri | http://hdl.handle.net/123456789/4854 | - |
| dc.description | 514-517 | en_US |
| dc.description.abstract | This study describes the kinetics and mechanism of free radical polymerization of vinyl acetate initiated by triphenyl stibonium 1,2,3,4-tetraphenylcyclopentadiene ylide in dioxane at 75±0.1°C under nitrogen atmosphere. The system followed ideal radical kinetics (Rp  [M] [I]0.5). The reaction has been retarded by hydroquinone, aniline and nitrobenzene. The overall activation energy and average value of kp2/kt are 32 kJ mol-1 and 0.46 l mol-1s-1, respectively. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | CSIR | en_US |
| dc.relation.ispartofseries | C08F18/08 | en_US |
| dc.source | JSIR Vol.65(06) [June 2006] | en_US |
| dc.subject | Ideal kinetics | en_US |
| dc.subject | Mechanism | en_US |
| dc.subject | Radical polymerization | en_US |
| dc.title | Kinetics and mechanism of polymerization of vinyl acetate using triphenyl stibonium 1, 2, 3, 4-tetraphenyl- cyclopentadiene ylide | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | JSIR Vol.65(06) [June 2006] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| JSIR 65(6) 514-517.pdf | 300.29 kB | Adobe PDF | View/Open |
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