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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Chen, Wen-Tong | - |
| dc.contributor.author | Zeng, Xi-Rui | - |
| dc.contributor.author | Xu, Ya-Ping | - |
| dc.contributor.author | Luo, Qiu-Yan | - |
| dc.contributor.author | Chen, Hua-Long | - |
| dc.date.accessioned | 2008-03-27T10:45:17Z | - |
| dc.date.available | 2008-03-27T10:45:17Z | - |
| dc.date.issued | 2008-01 | - |
| dc.identifier.issn | 0376-4710 | - |
| dc.identifier.uri | http://hdl.handle.net/123456789/527 | - |
| dc.description | 32-36 | en_US |
| dc.description.abstract | A new cyano-bridged praseodymiumIII-cobaltIII complex [Pr(DMSO)₅ (H₂O)₂](μ-CN)[Co(CN)₅]•H₂O, (1), has been syn-thesized via solution reaction and characterized by X-ray diffraction. The slightly distorted square-antiprism eightfold-coordinated Pr(III) and the approximately oriented octahedrally sixfold-coordinated Co(III) are linked by a cyano-bridge group to form a dinuclear complex. The [Pr(DMSO)₅(H₂O)₂](μ-CN)[Co(CN)₅] species are held together via hydrogen bonds to form a two-dimensional slab. The magnetic properties show that complex 1 exhibits antiferromagnetic interactions. IR and thermogravimetry-differential thermal analyses (TG-DTA) are also presented. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | CSIR | en_US |
| dc.relation.ispartofseries | Int. Cl. ⁸ C07F5/00; C07F15/06 | en_US |
| dc.source | IJCA Vol.47A(1) [January 2008] | en_US |
| dc.title | Synthesis, structure and properties of [Pr(DMSO)₅(H₂O)₂](μ-CN) [Co(CN)₅]•H₂O | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-A Vol.47A(01) [January 2008] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 47A(1) (2008) 32-36.pdf | 373.02 kB | Adobe PDF | View/Open |
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