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http://nopr.niscpr.res.in/handle/123456789/532| Title: | Synthesis and crystal structure of square-planar and mixed ligand octahedral nickel(II) O,O'-dicyclopentyl dithiophosphate complexes |
| Authors: | Taş, Murat Yağan, Mehtap Bati, Hümeyra Bati, Bekir Büyükgüngör, Orhan |
| Issue Date: | Jan-2008 |
| Publisher: | CSIR |
| IPC Code: | Int. Cl. ⁸ C07F15/04 |
| Abstract: | Ammonium O,O'-dicyclopentylphosphorodithioate (dcpdtp) has been synthesized from phosphorus pentasulphide and cyclopentanol in the presence of ammonia gas. Its complexes, I=[Ni(dcpdtp)₂] and II= [Ni(bp)₂(dcpdtp)2] (bp=4-benzylpiperidine), have been synthesized and their structures characterized by using UV-vis, IR spectroscopy, magnetic susceptibility measurements and X-ray single crystal structural analysis. The complexes crystallize in the triclinic system (space groups P ī) and exhibit a slightly distorted square planar [NiS₄] and trans-octahedral [NiS₄N₂] geometry for the complexes I and II, respectively. |
| Page(s): | 37-42 |
| ISSN: | 0376-4710 |
| Appears in Collections: | IJC-A Vol.47A(01) [January 2008] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 47A(1) (2008) 37-42.pdf | 483.67 kB | Adobe PDF | View/Open |
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