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http://nopr.niscpr.res.in/handle/123456789/56201| Title: | Organic-inorganic hybrid complexes of Lead(II) of sterically demanding heterocyclic β-diketones and flexible N-protected amino acids |
| Authors: | Maheshwari, Karuna Saxena, Sanjiv Jain, Asha |
| Keywords: | Lead(II) isopropoxide;Heterocyclic β-diketones;N-protected amino acids;Distorted trigonal bipyramidal geometry |
| Issue Date: | Feb-2021 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | A new set of organic-inorganic hybrid complexes of lead(II) of sterically demanding heterocyclic β-diketones and flexible N-protected amino acids of composition Pb[RC(O) CH3][ CHR'COO] (where R = C6H5, p-ClC6H4, CH3 and R’ = CH(CH3)C2H5, CH2CH(CH3)2 and CH(CH3)2 ) has been generated by the reactions of freshly prepared lead isopropoxide with sterically demanding heterocyclic β-diketones (LH) and flexible N-protected amino acids (AH) in 1:1:1 molar ratio in refluxing dry benzene . These lead(II) complexes of mixed organic ligands have been characterized on the basis of physico-chemical and spectroscopic studies. |
| Page(s): | 202-208 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.60A(02) [February 2021] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 60A(2) 202-208.pdf | Main Article | 738.41 kB | Adobe PDF | View/Open |
| IJCA 60A(2) 202-208_Suppl Data.pdf | Supplementary Data | 707.72 kB | Adobe PDF | View/Open |
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CH3][
CHR'COO] (where R = C6H5, p-ClC6H4, CH3 and R’ = CH(CH3)C2H5, CH2CH(CH3)2 and CH(CH3)2 ) has been generated by the reactions of freshly prepared lead isopropoxide with sterically demanding heterocyclic β-diketones (LH) and flexible N-protected amino acids (AH) in 1:1:1 molar ratio in refluxing dry benzene . These lead(II) complexes of mixed organic ligands have been characterized on the basis of physico-chemical and spectroscopic studies.