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http://nopr.niscpr.res.in/handle/123456789/59542| Title: | Hydrogen bonded molecular rectangle of N,N-bis(3-quinolyl- methylene)diphenylethanedionedihydrazone |
| Authors: | Patra, Goutam K Manna, Amit K De, Dinesh |
| Keywords: | Hydrazone;quinoline 3-carboxaldehyde;single-crystal X-ray;- stacking interactions;supramolecules |
| Issue Date: | Apr-2022 |
| Publisher: | NIScPR-CSIR, India |
| Abstract: | The title compound, N,N-bis (3-quinolylmethylene) diphenylethanedionedihydrazone (I) (molecular formula, C34H24N6) has been synthesized by the reaction of quinoline 3-carboxaldehyde and diphenylethanedionedihydrazone in 2:1 molar ratio. The molecular structure has been characterized by room-temperature single-crystal X-ray diffraction which reveals that two quinoline moieties are disposed nearly perpendicularly around the central C-C bond giving an ‘L’ shape to the molecule. This particular geometry gives rise to the hydrogen bonded supramolecular rectangle of two self-complementary molecules. These supramolecular units are further assembled by - interaction. |
| Page(s): | 416-419 |
| ISSN: | 2583-1321 (Online); 0019-5103 (Print) |
| Appears in Collections: | IJC Vol.61(04) [April 2022] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Indian J Chem, 61, 416-419 (Apr,2022).pdf | Main Article | 626.73 kB | Adobe PDF | View/Open |
| Indian J Chem, 61, 416-419 (Apr,2022) Suppl. Data.pdf | Supplementary Data | 512.23 kB | Adobe PDF | View/Open |
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