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http://nopr.niscpr.res.in/handle/123456789/59821| Title: | Synthesis and crystal structure of a distorted face sharing double cubane like tetranuclear NiII-Cu2 II-NiII compound derived from a reduced di-Schiff base ligand |
| Authors: | Hazari, Alokesh |
| Keywords: | Nickel(II);Copper(II);Tetranuclear;Reduced Schiff base;End-on azide |
| Issue Date: | May-2022 |
| Publisher: | NIScPR-CSIR, India |
| Abstract: | One new tetranuclear face sharing distorted double cubane like hetero-metallic NiII 2Cu2 II compound has been synthesized using a [NiLR] “metalloligand”, where H2LR = N,N'-bis(2-hydroxybenzyl)-1,3-propanediamine. The compound has been characterized by elemental analysis, spectroscopic methods and single crystal XRD. In the compound, in addition to the 2 -phenoxido bridges, the two terminal NiII atoms are linked to each of the central CuII ion by means of an end-on bridging azido (1,1-N3) ion separately, resulting a tetranuclear cubane like structure. |
| Page(s): | 465-471 |
| ISSN: | 2583-1321 (Online); 0019-5103 (Print) |
| Appears in Collections: | IJC Vol.61(05) [May 2022] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJC 61(5) 465-471.pdf | 944.28 kB | Adobe PDF | View/Open |
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