Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/62459| metadata.dc.identifier.doi: | https://doi.org/10.56042/ijc.v62i8.87 |
| Title: | Kinetics and mechanism of oxidation of cinnamyl alcohol by N-chloro p-toluene sulphonamide (Chloramine-T) in acid perchlorate medium |
| Authors: | Meena, Anita |
| Keywords: | Kinetics, Mechanism;Oxidation;Cinnamyl Alcohol;Chloramine-T |
| Issue Date: | Aug-2023 |
| Publisher: | NIScPR-CSIR, India |
| Abstract: | The kinetics of oxidation of cinnamyl alcohol by N-chloro-p-toluene sulphonamide (Chloramine-T) in an aqueous acid medium has been studied. The reaction is first order with respect to the oxidant but exhibits rate independence of substrate concentration. Rate is retarded by hydrogen ion concentration due to protonation of Chloramine-T. The product toluene-psulphonamide does not affect the rate of reaction. The cinnamyl aldehyde has been observed to be the oxidation product spectrally. |
| Page(s): | 803-807 |
| ISSN: | 2583-1321 (Online); 0019-5103 (Print) |
| Appears in Collections: | IJC Vol.62(08) [August 2023] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJC 62 (08) 803-807.pdf | 966.28 kB | Adobe PDF | View/Open |
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