Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/62902| metadata.dc.identifier.doi: | https://doi.org/10.56042/ijc.v62i11.4504 |
| Title: | Synthesis of novel binuclear Cu(II) complex and its application as catalyst for conversion of amine to imine |
| Authors: | Swargiary, Aieshri Mukherjee, Somali Brahma, Dulu Kalita, Pranjal Mondal, Arunendu |
| Keywords: | Cu(II) complex;2,3-Pyridinedicarboxylic acid;2,2ꞌ-Bipyridine;Catalyst;Benzylamine;Imine |
| Issue Date: | Nov-2023 |
| Publisher: | NIScPR-CSIR,India |
| Abstract: | Oxidative coupling reaction of benzylamine to imine has been achieved with almost 90% yield under very mild reaction conditions by applying a novel binuclear Cu(II) complex as a catalyst. Binuclear Cu(II) complex, [Cu2(2,3-pydc)(2,2ꞌ- bpy)4](ClO4)2.2H2O [A] has been synthesised using the ligands 2,3-pyridinedicarboxylic acid (2,3-pydc) and 2,2ꞌ-bipyridine (2,2ꞌ-bpy). The newly synthesised catalyst has been characterised by using single crystal X-ray diffraction study (SC-XRD), UV-Vis spectroscopy, IR-spectroscopy and elemental analysis. |
| Page(s): | 1186-1192 |
| ISSN: | 2583-1321 (Online); 0019-5103 (Print) |
| Appears in Collections: | IJC Vol.62(11) [November 2023] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJC 62(11) 1186-1192.pdf | 3.63 MB | Adobe PDF | View/Open | |
| IJC 62(11) 1186-1192_Suppl. Data.pdf | 650.55 kB | Adobe PDF | View/Open |
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