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http://nopr.niscpr.res.in/handle/123456789/641Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Deshmukh, Madhukar B | - |
| dc.contributor.author | Jadhav, Sunil D | - |
| dc.contributor.author | Kadam, Shashikant V | - |
| dc.date.accessioned | 2008-04-01T11:12:09Z | - |
| dc.date.available | 2008-04-01T11:12:09Z | - |
| dc.date.issued | 2007-06 | - |
| dc.identifier.issn | 0376-4699 | - |
| dc.identifier.uri | http://hdl.handle.net/123456789/641 | - |
| dc.description | 989-994 | en_US |
| dc.description.abstract | A mild method for the copper-catalyzed substitution of aldehyde acylals with organomanganese reagents is reported. This operationally simple C-C bond-forming protocol uses different Cu(I) catalysts. Acylal from trans-cinnamaldehyde furnishes conjugated addition product when reacted with alkyl and aryl organomanganese reagents in presence of 10 mol % of Cu(NCMe)₂(PPh₃)₂[BF₄] and 2 equivalent of Me₃Si-Cl as an accelerator. This reagent can be efficiently used in the substitution of one acetate group of aromatic acylal to form esters in high yield. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | CSIR | en_US |
| dc.source | IJCB Vol.46B(6) [June 2007] | en_US |
| dc.subject | Substitution | en_US |
| dc.subject | Acylals | en_US |
| dc.subject | Organomanganese reagents | en_US |
| dc.title | Copper-catalyzed substitution reactions of acylal with organomanganese reagents | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-B Vol.46B(06) [June 2007] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCB 46B(6) (2007) 989-994.pdf | 140.11 kB | Adobe PDF | View/Open |
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