Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/65395| metadata.dc.identifier.doi: | https://doi.org/10.56042/ijc.v64i2.15867 |
| Title: | DBU-mediated C-C bond formation between Baylis-Hillman acetates and active methylene compounds |
| Authors: | Tashi Khom, Sonam Saikia, Pranjit Nath Yadav, Nagendra |
| Keywords: | Baylis-Hillman acetates;SN2ʹ Substitution;DBU;Active methylene compounds;Tri-substituted alkenes |
| Issue Date: | Feb-2025 |
| Publisher: | NIScPR - CSIR |
| Abstract: | A new reagent system for the formation of C-C bond between the Baylis-Hillman acetates and active methylene compounds (AMCs) has been developed. This method provides tri-substituted alkenes as the major product in good yield under neat condition. The reaction proceeds through the SN2ꞌ mechanism to give substituted alkenes in good yields with high stereoselectivity. 1,8-Diazabicyclo(5.4.0)undec-7-ene (DBU) acts as a unique base which accelerates the rate of the reaction. |
| Page(s): | 225-231 |
| ISSN: | 2583-1321 (Online); 0019-5103 (Print) |
| Appears in Collections: | IJC Vol.64(02) [Feb 2025] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJC 64(2) 225-231.pdf | 1.31 MB | Adobe PDF | View/Open | |
| IJC 64(2) 225-231 Suppl. Data.pdf | 2.02 MB | Adobe PDF | View/Open |
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