Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/65753| metadata.dc.identifier.doi: | https://doi.org/10.56042/ijc.v64i4.15225 |
| Title: | Applications of oxidative and reductive methodologies on coumarinyl ketones |
| Authors: | Shit, Ranjit Kumar Sinha, Nitai Chand |
| Keywords: | Assorted;Chemoselectivity;Derivatives;Epoxides;Oxidation;Reduction;Unusual |
| Issue Date: | Apr-2025 |
| Publisher: | NIScPR-CSIR, India |
| Abstract: | The higher degree of chemoselctivitiy and regioselectivity recorded during the selenium dioxide oxidation of various coumarinyl ketones 1-7 affords the corresponding coumarinyl α-di carbonyl compounds 1a-7a and 5b in which the compound 2a has been isolated as an unexpected product and also the sodium borohydride reduction of coumarinyl ketones 1-14 affords the desired coumarinyl carbinols 1c-3c, 5c, 7c-9c, 11c and 13c and 5-keto-6-hydroxy-cinnamic acid derivatives 4d, 6d, 10d, 12d and 14d as unexpected products in minor amounts. |
| Page(s): | 441-446 |
| ISSN: | ISSN: 2583-1321 (Online);ISSN: 0019-5103 (Print) |
| Appears in Collections: | IJC Vol.64(04) [April 2025] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJC 64(4) 441-446.pdf | 4.33 MB | Adobe PDF | View/Open | |
| IJC 64(4) 441-446 Suppl. Data.pdf | 523.12 kB | Adobe PDF | View/Open |
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