Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/6635| Title: | An enantiospecific synthesis of 2-pupukeanone |
| Authors: | Srikrishna, A Kumar, P Ravi Gharpure, S J |
| Keywords: | Pupukeananes;marine sesquiterpenes;Michael-Michael reaction;rhodium carbenoid;intramolecular CH-insertion |
| Issue Date: | Aug-2006 |
| Publisher: | CSIR |
| IPC Code: | Int. Cl.8 C07C |
| Abstract: | A combination of intermolecular Michael addition followed by intramolecular Michael addition of an enone to methyl acrylate and an intramolecular rhodium carbenoid CH insertion reaction of a diazo ketone have been exploited for the construction of isotwistanes. It has been extended to racemic and enantiospecific synthesis of 2-pupukeanone. |
| Page(s): | 1909-1919 |
| ISSN: | 0975-0983(Online); 0376-4699(Print) |
| Appears in Collections: | IJC-B Vol.45B(08) [August 2006] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCB 45B(8) 1909-1919.pdf | 173.09 kB | Adobe PDF | View/Open |
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