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http://nopr.niscpr.res.in/handle/123456789/673| Title: | An RCM based approach to (±)-herbertene-1, 14-diol and (±)-tochuinyl acetates |
| Authors: | Srikrishna, A Rao, M Sreenivasa |
| Keywords: | Terpene synthesis;Vicinal quaternary carbons;Claisen rearrangement;Ring-closing metathesis;Herbertanes;Cuparanes |
| Issue Date: | Aug-2007 |
| Publisher: | CSIR |
| Abstract: | A sequence comprising of Johnson's ortho ester Claisen rearrangement, alkylation and RCM reactions has been developed for the synthesis of cyclopentenes containing vicinal quaternary carbon atoms. The versatility of the sequence has been demonstrated by the efficient total synthesis of sesquiterpenes tochuinyl acetates and herbertene-1,14-diol. |
| Page(s): | 1308-1317 |
| ISSN: | 0376-4699 |
| Appears in Collections: | IJC-B Vol.46B(08) [August 2007] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCB 46B(8) (2007) 1308-1317.pdf | 159.9 kB | Adobe PDF | View/Open |
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