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http://nopr.niscpr.res.in/handle/123456789/6785| Title: | Kinetics of elimination reactions of 1-chloro-1-(4-methoxyphenyl)-2-phenylethane in acetonitrile |
| Authors: | Kumar, D Santhosh Balachandran, S |
| Keywords: | Kinetic study;elimination reaction;dehydrochl-orination;phenylethane;trans-p-methoxy stilbene;acetonitrile |
| Issue Date: | Dec-2006 |
| Publisher: | CSIR |
| IPC Code: | Int.Cl.8 C07D |
| Abstract: | 1-Chloro-1-(4-methoxyphenyl)-2-phenylethane undergoes dehydrochlorination in acetonitrile to give trans-p-methoxy stilbene by E1 mechanism. The presence of electron donating p-methoxy group and the delocalisation of charge throughout the structure proposes a stable cation. The mass law effect and special salt effect are characteristic for a reaction involving the stable cation and these effects have been reported for the first time in a pure E1 reaction. |
| Page(s): | 2751-2753 |
| ISSN: | 0975-0983(Online); 0376-4699(Print) |
| Appears in Collections: | IJC-B Vol.45B(12) December 2006] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCB 45B(12) 2751-2753.pdf | 149.33 kB | Adobe PDF | View/Open |
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