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http://nopr.niscpr.res.in/handle/123456789/697| Title: | Pyrrolidine catalyzed regioselective and diastereoselective direct aldol reaction in water |
| Authors: | Mahajan, Dinesh Chimni, Swapandeep Singh |
| Keywords: | Direct aldol reaction;Pyrrolidine catalysis;Regioselective synthesis;Diastereoselective synthesis;Aqueous media;Organocatalysis |
| Issue Date: | Aug-2007 |
| Publisher: | CSIR |
| Abstract: | Pyrrolidine catalyzed direct aldol reaction of methyl ketones other than acetone with 4-nitrobenzaldehyde in water affords linear aldol addition product arising from the selective attack of the unsubstituted carbon of the unsymmetrical ketone. The present methodology provides an experimentally simple and green process for regioselective synthesis of -hydroxyketones in water. |
| Page(s): | 1355-1358 |
| ISSN: | 0376-4699 |
| Appears in Collections: | IJC-B Vol.46B(08) [August 2007] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCB 46B(8) (2007) 1355-1358.pdf | 139.12 kB | Adobe PDF | View/Open |
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