Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/8976Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Sengupta, Saumitra | - |
| dc.contributor.author | Mondal, Somnath | - |
| dc.date.accessioned | 2010-05-14T11:36:04Z | - |
| dc.date.available | 2010-05-14T11:36:04Z | - |
| dc.date.issued | 2005-03 | - |
| dc.identifier.issn | 0975-0983(Online); 0376-4699(Print) | - |
| dc.identifier.uri | http://hdl.handle.net/123456789/8976 | - |
| dc.description | 553-556 | en_US |
| dc.description.abstract | A new stereoselective synthetic route to a -hydroxyalkyl- 2-butenolide has been described starting from the -hydroxy acid
chiral pool and via the intermediacy of an enantiopure -hydroxy- -ketosulfone. A
non-chelation controlled borohydride reduction (80% de) step is the key to the
high diastereoselectivity observed in this synthesis. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | CSIR | en_US |
| dc.relation.ispartofseries | Int.Cl.7 C 07 D 307/26 | en_US |
| dc.source | IJC-B Vol.44B(03) [March 2005] | en_US |
| dc.title | A chiral pool based synthetic strategy for -hydroxyalkyl- 2-butenolides | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | IJC-B Vol.44B(03) [March 2005] | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCB 44B(3) 553-556.pdf | 57.42 kB | Adobe PDF | View/Open |
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.
-hydroxyalkyl-
2-butenolide has been described starting from the
-hydroxy acid
chiral pool and via the intermediacy of an enantiopure
-ketosulfone. A
non-chelation controlled borohydride reduction (80% de) step is the key to the
high diastereoselectivity observed in this synthesis.