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http://nopr.niscpr.res.in/handle/123456789/15491| Title: | Silyl - nitrogen compounds: Part (XI)Synthesis of silylated metallahydrazines |
| Authors: | Vasisht, S K Kaushal, Jyotsna |
| Issue Date: | Aug-2000 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Reactions of lithium tris(trimethylsilyl)hydrazine (1) with ECl3 (E= AI, Fe) and Me2SnCI2 show that (1) undergoes substitution reaction to give stable silylated metallahydrazines, (Me3Si)2N-N(SiMe3)AICI2 and (Me3Si)2N-N (SiMe3)2 SnC1(Me2), whereas, FeCI3 acts as an oxidant to give Me3SiN=NSiMe3 . However, EX4 (E = Sn, Ti and X= CI, I) and SbCI5 provide disubstituted products [(Me3Si)2N-N(SiMe3)2EXn-2. SnCI2, gives a two coordinated Sn(II) derivative Sn[(Me3Si) 3N2] 2. |
| Page(s): | 863-866 |
| Appears in Collections: | IJC-A Vol.39A(08) [August 2000] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 39A(8) 863-866.pdf | 696.91 kB | Adobe PDF | View/Open |
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