Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/15843| Title: | Synthesis and characterization of spirobicyclic hypervalent phosphorus species : X-ray structural study of a dibenzoxazaphosphole |
| Authors: | Anand, B N Bains, Rajwant Venugopalan, P |
| Issue Date: | Sep-1999 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Reaction of
pentachlorophosphorane with o-Aminophenol
in 1:2 mole ratio under controlled temperature conditions yields a
spirobicyclic phosphorane (1) in
which a five-membered ring with oxygen and nitrogen bonded to a pentavalent phosphorus.
However, at higher temperatures of the reaction, a benzoxazaphosphole (2)
is isolated which crystallises in a
triclinic system,
space group P‾1 and has structural
parameters of a =
8.2932 (8) Å, b =
9.4138(9 ) Å, c =10.4382(10) Å and  =96.073(2)°,
β= 108.303(1)°,  =112.785(1)°.
R1 = 0.0610, wR2 = 0.1178 for 1574 reflections [1> 2 σ (I)]. |
| Page(s): | 874-879 |
| Appears in Collections: | IJC-A Vol.38A(09) [September 1999] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 38A(9) 874-879.pdf | 2.1 MB | Adobe PDF | View/Open |
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